Multimetallic catalysed cross-coupling of aryl bromides with aryl triflates. A catalytic system using two metals allows the synthesis of biaryl products using two. An efficient method for palladium-catalyzed cross-coupling of aryl chlorides and triflates with sodium cyanate is reported. The protocol allows for the synthesis of. ADVERTISEMENT. Log In Register This article highlights the Cross-Coupling of Aryl Bromides with Aryl Triflates. A polystyrene-supported triflating reagent for the synthesis of aryl triflates on ResearchGate, the professional network for scientists. The palladium-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) has been developed using dialkylbiaryl phosphine. Practical Synthesis of Aryl Triflates under Aqueous Conditions Doug E. Frantz*, Damian G. Weaver, James P. Carey, Michael H. Kress and Ulf H. Dolling Transition Metal Catalyzed Synthesis of Arylamines and Aryl Ethers from Aryl Halides and Triflates. Hua Wang, Copper-Catalyzed Domino Synthesis of Nitrogen. Page 1. Decarboxylative Biaryl Synthesis from Aromatic Carboxylates and Aryl Triflates Lukas J. Goossen,* Nuria Rodrı ´guez, and Christophe Linder An insoluble polystyrene-supported triflating reagent has been prepared. allows for the efficient synthesis of aryl triflates from a wide range of phenols in a.